Announcements

Sat. 16dec17:
***  Thanks for being such a great class! ***
Final Grades have been entered and will be available when the Registrar releases them.
Best Wishes to you all for the Holidays!
--Cheers,
Prof. Callis

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Note: The FINAL Starts promptly  at 4:00 pm tomorrow, Tuesday Dec 12

OFFICE HOURS Tue Dec 12:  9-10,    11:30-12:00,    2:15-3:00

Correction to Problem 3. of 2012 Final Exam Solutions: Delta H = -20000 J + (1atm)(1000 L)

 

 

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Correction to Prob.#1, Ex4 of 2012: Answer is same but process had an error.

CORRECTION HW#7 Prob. 3. (a)17C-2H should be 17O-2H

Schedule for last 3 weeks posted as Handout#10

Homework #6, due Tue Nov. 21, is posted as Handout #9

Exam 3 Solutions are posted.

Graded HW#5 is hanging on the door of 55 CBB.

Solutions for HW#5 are posted.

Objectives for Exam 3, Thur, are posted as Handout #8 below.

Solutions for HW#3 and HW#4 are posted under HW and Exam Solutions below

***HW#5 CLARIFICATION***: Prob. 5: f = frictional coef., q = charge, m = mass

1:30 pm Sunday : HW #5 is posted as Handout #7

4:48 pm Thur.  CORRECTION on Problem 6. (a) and (b): See Handout 6a HW$#4 -corrected

***HOMEWORK #4 IS NOW DUE ON FRIDAY Oct 27!!!!

Homework #4 is posted as Handout #6 (2:48 pm Thur 19oct)

Fri. 6oct 2:41 pm:Correction to Correction:  the correction was to prob 8 , not 4(c).

Fri. 6oct a couple of corrections have been made to HW#3, problem 4(c) and S4.  See the new post.  
CORRECTION: Reading for tomorrow  for Friday Oct 6 = pp:  241-242 (not 141-142)

Objectives for Exam 2 (Friday the 13th) are posted as Handout #5
Homework assignment  # 3 is posted as Handout #4.
Reading assignments for next week are posted.
Note a small, non-important typo on the last paragraph of Prob. 3.S4 of homework #2:
             ...  A, B, C, D, and E ... should have been ... B, C, D, E, and F ...
Exam 1 solutions are now posted under Homework and Exam Solutions below
Homework #2 is posted as Handout #3
Office hours are 2-5 this afternoon.(Monday 18sept.)
2016 Exams are now posted under Old Exams
Solutions to HW#1 are posted below under Homework and Exam Solutions 2017 
Handout #2: Objectives for Exam 1 is now posted
Office hours today Mon   11sep  9:30-10:30, 2-3,  4-5
Office hours today Fri     8sep  10:20-12, 1-3,  4:15-5:15
Office hours today Thur 7sep 9:30-10:30
STARTING  Friday Sept 1 this class  meets in Roberts 321 (a larger room)
*** The course cap has been increased to 49;  it is no longer full and it is now possible to register for chmy 361
Homework #1 is posted as Handout #1a on Monday, Aug 28 at 3 pm

Reading Assignments

Chapter 3.
Lectures 9-10 Tues.,Thurs   Sept. 12 and 14: sep17 pp 55-61
Lecture 11  Fri 15sep17  pp 62-71
Lecture 12   Thur.  21sep17: pp72-75
Lecture 13   Fri.  22sep17: pp 75-80(top half)
Lecture 14   Mon. 25sep17 pp 87-90(Partial Derivatives)
Lecture 15   Tue. 26sep17 pp 80-87(Non-Covalent “Reactions”)

Chapter 4.
Lecture 16   Thur: 28sep17 pp 101-104 Gibbs Energy
Lecture 17    Fri.   29sep17  pp 104(bottom)-107 Gibbs Energy and Kequil
Lecture 18    Mon.  2oct17     pp 108(bottom)-119 (Non-ideal gases, activity, standard states, biochemical standard state)
Lecture 19    Tue.   3oct17     pp 126(bottom)-129 (Kequil vs. T;; 140(bottom)-142 (DNA melting T); 133-134 ( buffers)

Chapter 5.
Lecture 20    Thur.  5oct17     pp 162,191 Boltzmann distribution; p 24 equipartition, quantum effects on heat capacity
Lecture 21    Fri.     6oct17 pp 135-138 Thermo. of metabolism;Chapter 7241-242 Electrochem. cells and work

Chapter 7

Lecture 22   Mon.  9oct17 pp 243-247 Standard reduction potentials, free energies, and Nernst equation.

Chapter 6
Lecture 23   Tue.  10oct17 196-204 Phase equilibria I
Lecture 24   Mon Oct 16: pp 200(bottom)-207 Vapor Pressure vs T; Solute Transfers:Henry's Law
Lecture 25  Tue    Oct 17: p200 Phase Rule;pp207-213 Partition coefficients; Scatchard Plots;Hill coef.
Lecture 26  Thur  Oct 19: pp214-224; Surface Tension, Hydrophobic Effect;Membranes;
Oct 19: Ch. 7pp247-252 Transmembrane equilibria; Na+,K+ pumping
Lecture 27  Fri      Oct 20: pp248-252 Colligative properties

Chapter 8

Lecture 28  Mon  Oct 23: Ch 8: pp 252-156 Maxwell Boltzmann (optional); pp264-268:Ave speed;collisions per second;mean free path.
Lecture 29 Tue   Oct 24:   pp 269-76 Diffusion and Frictional Coef.:
Lecture 30 Thur Oct 26:  pp 285-287, 292-294: Viscosity, pp278-281, 283:Sedimentation 
Lecture 31 Fri    Oct 27:   pp 292-294: Protein Electrophoresis
Lecture 32 Mon Oct 30:  pp 288-291: DNA Electrophoresis and sequencing
Chapter 9Lecture 33 Tue Oct 31:  pp 305-316 First order kinetics; 327-329;337-338: Mechanisms; 333bottom-335:Microscopic reversibility;
pp 338-340:Temperature Dependence
Lecture 34  Thur Nov 2 pp354-355: Diffusion controlled reactions; pp 358-363: Photochemistry;
Chapter 10 pp 378-381: Enzymes I
Lecture 35  Fri  Nov 3 pp 382-385: Enzymes II; Chapter 12  466-469: Electrostatics; Chapter 13 pp 489-493:Light I
Lecture 36  Mon  Nov 6 pp 382-385: Enzymes III; Chapter 13 pp 489-502:Light-molecule interactions and Beer-Lambert Law
Tue Nov.6 Review for Exam 3 (which is on THURSDAY, NOV 9)
Thur Nov. 9 EXAM 3
Friday Nov. 10 Veterans Day Holiday (classes don't meet)
Lecture 37  Mon  Nov 13 pp 502-519 Protein & DNA UV spectra; DNA Hypochromism; Fluorescence; Lifetime; Quenching; FRET;  Single-molecule fluorescence
Lecture 38  Tue  Nov  14 pp 520-525: CD;
Lecture 39  Thur Nov 16  pp 526-530  Vibrational spectroscopy; Chapter 14 pp 539-543: NMR
Lecture 40  Fri     Nov 17  pp 544-548: NMR spectrum and Chemical shifts; pp 562(bottom)-566 MRI

Lecture 41  Mon Nov 20 Review MRI for HW problem; then back to pp 542, 544-546 with Boltzmann and quantum ideas

Lecture 42 Tue   Nov 21

 

 

 

Lectures 2017

Lec 1 Mon 28aug17 Course Introduction
Lec 2 Tue  29aug17 System, Surroundings, Universe, Heat vs. Work
Lec 3 Thur 31sep17 Bio-work; Calculating work and pressure.
Lec 4  Fri   1sep17 Heat Capacity; Ideal gas Kinetic Energy vs. Temperature
Lec 5 Tue  5sep17 State, State functions, reversible vs. irreversible paths 
Lec 6 Thur  7sep17  Microscopic : Work from KE of molecules; Equations of State; Enthalpy
Lec 7 Fri     8sep17  Cp;  Chemical Reactions; Heats of formation; Standard States; Hesses Law; Bond Enthalpies
Lec 8 Mon 11sep17  Homework help; Partial Pressure; Vapor Pressure
Lec 9 Tue 12sep17  Boiling in detail; more Vapor Pressure; Intro 2nd Law and Carnot Cycle
Lec 10 Thur 14sep17  Heat Pump vs. Heat Engine; calculating entropy: dS = dqrev/T
Lec 11 Fri  15sep17  Using 2nd Law; 3rd Law&Molecular Interpretation
Lec 12 Thur 21sep17  "Free" Energy Functions; The Fundamental Equation
Lec 13 Fri 22sep17 Partial Derivatives I: G vs T and P; 
Lec 14 Mon 25sep17 Partial Derivatives II
Lec 15 Tue 26sep17 Non-covalent "reactions", proteins, and DNA 
Lec 16 Thur 28sep17 More proteins; DNA;chemical potential; Gibbs energy of reactions and equilibrium
Lec 17 Fri  29sep17 Qualitative and Quantitative LeChatelier;Standard States; Units of Q; Finding Keq
Lec 18 Mon  2oct17 The Real Q; Activity; activity coef; Biol. Standard state; Temperature Dependence of Keq:Van't Hoff 
Lec 19 Tue  3oct17  duplex DNA association/dissociation; Buffers
Lec 20 Thur 5oct17  Boltzmann distribution and Keq from Gibbs; Equipartion,Quantum Mech. and Heat Capacity
Lec 21 Fri     6oct17  Hesses Law for Table 4.3; Overview of energy in biology; Electrochem. I
Lec 22 Mon 9oct17  Electrochem II:Finding E0 and delta G0 for a reaction.
Lec 23 Tue  10oct17 Intro to Phase Equilibria; Solvent transfers
-------    Thur 12oct17 Review for Exam 2
Lec 24 Mon 16oct17 Vapor Pressure vs T; Solute Transfers:Henry's Law
Lec 25 Tue   17Oct 17: Phase Rule;Partition coefficients; Scatchard Plots;Hill coef.;lipids
Lec 26 Thur 19Oct17 Surface Tension, Hydrophobic Effect;Membranes; Transmembrane equilibria; Na+,K+ pumping
Lec 27  Fri   20Oct17 Colligative Properties
Lec 28 Mon 23oct17 Maxwell -Boltzmann; Ave. speed; collisions per second; mean free path
Lec 29 Tue  24oct17 Mean free path; Diffusion and Frictional Coef.
Lec 30 Thur 26Oct17 Sedimentation; Viscosity;  
Lec 31 Fri  27Oct17 Protein Electrophoresis
Lec 32 Mon 30Oct17 DNA Electrophoresis; Kinetics I
Lec 33 Tue  31Oct17 First Order; Mechanisms; MicroscopicReversibility;TemperatureDependence;Diffusion Controled;
Lec 34 Thur 2Nov17 Photochemistry; Enzymes I
Lec 35 Fri  3Nov17 Enzyme kinetics II; Electrostatics
Lec 36 Mon 6Nov17 Enzyme-Electrostatics; Light I
Lec 37  Mon  13nov17 Protein UV; Beer's Law; Fluorescence I; Lifetime; Quenching; Phosphorescence
Lec 38  Tue   14nov17 DNA Hypochromism; single molecule fluorescence; FRET; vision;CD;
Lec 39  Thur  16nov17 Vibrational spectroscopy; NMR I
Lec 40  Fri     17nov17 NMR II;  MRI I
Lec 41  Mon  20nov17 Review MRI; Understanding NMR with Boltzmann and Quantum mechanics
Lec 42  Tue   21nov17 More pulsed NMR; Intro to Quantum Mechanics
Lec 43 Mon  27nov17 Quantum Concepts, wave nature of particles
Lec 44 Tue   28nov 17 Climate Science I
Lec 45 Mon   4Dec17  Climate Science II
Lec 46 Thur  7Dec17 Review 1
Lec 47 Fri      8Dec17 Review 2

 

Handouts 2017

 

 

Handouts 2016

 

Homework and Exam Solutions 2017

Homework #1 Solutions
Exam#1 Solutions
Homework #2 Solutions
Exam#2 Solutions
Homework #3 Solutions
Homework #4 Solutions
Homework #5 Solutions
Exam #3 Solutions
Homework #6 Solutions

Homework #7 Solutions

Exam #4 Solutions

 

Lectures 2016

Lec 1 Mon 29aug16 Course Introduction
Lec 2 Tue 30aug16 System, Surroundings, Universe, Heat vs. Work
Lec 3 Thur 1sep16 Bio-work; Calculating work and pressure.
Lec 4  Fri   2sep16 Heat Capacity; Ideal gas Kinetic Energy vs. Temperature 
Lec 5 Tue  6sep16 State, State functions, reversible vs. irreversible paths
Lec 6 Thur  8sep16  Microscopic : Work from KE of molecules; Equations of State; Enthalpy
Lec 7 Fri     9sep16  Cp;  Chemical Reactions; Heats of formation; Standard States; Hesses Law; Bond Enthalpies
Lec 8 Mon 12sep16  Homework help; Partial Pressure; Vapor Pressure; Boiling
Lec 9 Tue 13sep16  Boiling in detail; more Vapor Pressure; Intro 2nd Law and Carnot Cycle
Lec 10 Thur 15sep16  Heat Pump vs. Heat Engine; calculating entropy: dS = dqrev/T
Lec 11 Fri  16sep16  Using 2nd Law; 3rd Law
Lec 12 Thur 22sep16 "Free Energy Functions; The Fundamental Equation
Lec 13 Fri 23sep16 Partial Derivatives I: G vs T and P; 
Lec 14 Mon 26sep16 Partial Derivatives II 
Lec 15 Tue 27sep16 Non-covalent "reactions", proteins, and DNA
Lec 16 Thur 29sep16 More proteins; DNA;chemical potential; Gibbs energy of reactions and equilibrium
 Lec 17 Fri  30sep16 Qualitative and Quantitative LeChatelier;Standard States; Units of Q; Finding Keq 
 Lec 18 Mon  3oct16 The Real Q; Activity; activity coef; Biol. Standard state; Temperature Dependence of Keq:Van't Hoff 
Lec 19 Tue  4oct16  duplex DNA association/dissociation; Buffers I
Lec 20 Thur 6oct16  Boltzmann distribution and Keq from Gibbs; Equipartion,Quantum Mech. and Heat Capacity
Lec 21 Fri    7oct16  Hesses Law for Table 4.3; Overview of Energy in Biolgy; Electrochem I
Lec 22 Mon 10oct16  Electrochem II:Finding E0 and delta G0 for a reaction.
Lec 23 Tue  11oct16 Nernst Eq; Intro to Phase Equilibria
Lec 24 Mon 17oct16 Phase Rule;Solvent Transfers
Lec 25 Tue  18oct16 Vapor Pressure vs T; Solute Transfers:Henry's Law
Lec 26 Thur 20oct16 Partition coefficients; Scatchard Plots; Pumping ions
Lec 27 Fri    21oct16 Active transport across membranes; Colligative properties
Lec 28 Mon 24oct16 Osmotic Pressure II;Freezing point depression; Donnen potential; Maxwell Boltzmann
Lec 29 Tue  25oct16  Ave speed;collisions per second;mean free path; Diffusion I
Lec 30 Thur 27oct16 Diffusion and Frictional Coef.; Intro. Sedimentation.
Lec 31 Fri    28oct16 Sedimentation, Intro to Electrophoresis
Lec 32 Mon 31oct16 Electrophoresis II
Lec 33 Tue   1nov16 DNA electrophoresis; Fingerprinting; Kinetics I
Lec 34  Thur 3nov16 First order kinetics; Mechanisms; Microscopic reversibility; Temperature Dependence
Lec 35  Fri    4nov16 Diffusion controlled reactions; Photochemistry; Enzymes I
Lec 36  Mon 14nov16 Enzymes II; Electrostatics; Light I
Lec 37  Tue  15nov16 Light II; Beer's Law; Fluorescence I
Lec 38  Thur 17nov16 Fluorescence II; Lifetime; Quenching; FRET; DNA Hypochromism; Single-molecule fluorescence
Lec 39   Fri   18nov16 Single molecule II; Vision; Circular Dichroism;Molecular Vibrations; Light scattering
Lec 39  25nov16  with new slide 16  is helpful for Prob 3 of HW #7  
Lec 40  Mon  21nov16 Raman vs IR; Intro to NMR; Intro to MRI
Lec 41 Tue    22nov16 MRI II;NMR II: Intro to Fourier Transform NMR
Lec 42 Mon   28nov16 NMR III: a more accurate view;  Quantum Mechanics I
Lec 43 Tue    29nov16 Quantum Mechanis II: concepts, Schrodinger Eq, particle diffraction
Lec 44 Mon    6dec16  Why the sky is blue (on final); Climate Physical Chemistry (NOT on final)
Lec 46 Corrected p. 5   11dec16  Review of Biochem option topics

Old Exam Keys

Links

 

 

 

Direct questions to pcallis@montana.edu
Room 55 CBB
Phone 994-5414

 

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Updated on: 26Aug2016 at 4:12 PM

Lecture 24   Mon-Tue Oct 16: pp 200-208